Polymers, either synthetic or natural, are present in every
aspect of our daily lives. Table 1 shows brief history of
polymer development. Many modern functional materials,
pharmaceutical equipments, electronic devices, automobile
parts, etc., have polymeric components. Polymers are
replacing traditional materials because of their low cost
and special applications. Figure 1 shows the increment of
the world-wide production of polymers from 1950 to 2002.
Table 1. The history of polymers in brief.
19th century |
Natural polymer and derivatives (vulcanized
rubber, celluloid) |
1920 |
Concept of macromolecules postulated by Staudinger |
1930-1940 |
First systematic synthesis of polymers |
1940-1950 |
Synthetic rubbers and synthetic fibers |
1950-1960 |
Stereospecific polymerizations by Ziegler and
Natta, the birth of polypropylene |
1960-1970 |
Discovery of PPO at GE by Hay and commercialization of PPO/PS blends (Noryl) |
1970-1980 |
Liquid-crystalline polymers |
1980-1990 |
Super strong fibers (Aramid, polyethylene) |
1990-2000 |
Novel polyolefins hybrid systems
(polymerlceramic, polymer/metals),
Nature-inspired catalysts, Living free radical
polymerization. |
2000- |
Synthesis of polymers by bacteria and plants |
Figure 1. World-wide production of crude steel and polymers (source www.vke.de)
Automotive industry Motorists want high-performing cars
combined with reliability, safety, comfort, competitive
pricing, fuel efficiency, and, increasingly, reassurance
about the impact on the environment. Lightweight polymeric
materials. Are increasingly used in this sector (Daimler
Benz's Smart is a nice example), also contributing to a 10%
reduction in passenger fuel consumption across Europe.
Building and construction Polymeric materials are used in
the building and construction sector, for example for
insulation, piping, and window frames. In 2002 this sector
accounted for 17.6% of the total polymer consumption.
Electrical and electronic industry Many applications in this
field arise from newly designed polymeric materials, for
example for polymeric solar cells and holographic films. It
is interesting to note that, while the number of
applications in this field is increasing, the weight of the
polymers used per unit is decreasing.
Packaging The packaging sector remains the largest consumer
of synthetic polymers, approximately 38% of the total
market. This is mainly due to. the fact that these materials
are lightweight, flexible, and easy to process, and are
therefore increasingly being substituted for other
materials. Although polymer packaging ranks first in terms
of units sold, it is only third if judged on weight.
Agriculture As agricultural applications account for about
2.5% of the total of synthetic polymers consumed in Europe,
they play only a marginal role. Irrigation and drainage
systems provide effective solutions to crop growing, and
polymeric films and greenhouses can increase horticultural
production substantially. The use of so called "super
absorbers" for increased irrigation efficiency in arid areas
can be considered an important emerging market.
Tables 2 and 3 present some polymers with their
applications.
Table. 2. Applications for the major thermoplastics [2].
Thermoplastic
|
Applications |
Low density polyethylene (LDPE ) |
Pallet and agricultural film, bags, toys, coatings, containers, pipes |
Polypropylene (PP) |
Film, battery cases, microwave-proof containers, crates, automotive parts, electrical components |
Polyvinyl chloride (PVC) |
Window frames, pipes, flooring, wallpaper, bottles, cling film, toys, guttering, cable insulation, credit cards, medical products |
High density polyethylene (HDPE) |
|
Polyethylene terephthalate (PET) |
Bottles, textile fibers, film food packaging |
Polystyrene (PS/EPS) |
|
Polyamide (PA) |
Film for food packaging (oil, cheese, "boil-in-bag"), high-temperature engineering applications, textile fibers |
Styrene copolymers (ABS/SAN) |
|
Polymethylmethacrylate (PMMA) |
Transparent all-weather sheet, electrical insulators, bathroom units, automotive parts |
Table. 3. Applications for the major
thermosets [2].
Thermosets
|
Applications |
Polyurethane (PU) |
Coatings, finishes, cushions, mattresses, vehicle seats |
Phenolics |
General appliance moldings, adhesives,
appliances, automotive parts, electrical
components |
Epoxy resins |
Adhesives, automotive components, E&E components, sports equipment, boats |
The development of new polymers and the modification and
enhancement of the old ones are goals of many researchers in
both industry and academia. A breadth of knowledge has been
built over the years which involve aspects of organic
chemistry, physical chemistry, analytical chemistry,
physics, chemical and mechanical engineering. Those sciences
are integrated to support the in-depth analysis of polymer
synthesis, structure, kinetics, characterization, and
processing in order to relate to the performance of the
polymer in end use. If polymer chains are completely
characterized and the structural basis of its properties are
known, the polymerization reaction can be optimized and
controlled to produce the optimum properties from a
particular chemical system.
[1] Handbook of polymer reaction engineering (2005)
[2] Association of Plastics Manufacturers in Europe. (2002)