| 2. Understanding Corrosion | |
|
2.5.4 Exchange Current Density [2/2] |
|
Example:
The exchange current density for H+
+ e
H2 on
Mercury is 10-14 A/cm2, but is several orders of
magnitude higher on Platinum at 10-2 A/cm2. A large
current density means a very stable potential which cannot be easily
disturbed, hence, Platinized platinum is made a standard hydrogen electrode,
so that the potential remains stable.
Figure below shows the exchange current density values for hydrogen reduction on Hg, Fe and Pt and overvoltage hc Vs i (current density).
|
|