5. Cathodic Protection

5.3 Cathodic Protection Systems [2/8]


Galvanic anodes

Following are the characteristics of the galvanic anodes commonly used.

Table 5.1: Characteristics of Galvanic Anodes

Metal Atomic Weight Equivalent Weight

Theoretical current output

amp/hr/lb (amp/hr/kg)

Magnesium 24.3 12.15 1000 (2200)
Zinc 65.4 32.7 372 (820)
Aluminum 27.0 13.5 1300 (2970)

The efficiency of magnesium anodes is about 50% , the current output is 500 amp/hr/lb. Zinc oxide operates at an efficiency of 90% and its current output is 335 amp/hr/lb. The efficiency of aluminum anode is about 75% and its current output is 1000 amp/hr/lb.

Typical compositions of magnesium and zinc anodes are given in the following tables.

Table 5.2: Composition of Magnesium Anode

Element Percentage (%)
Aluminum 0.010 max
Manganese 0.50 to 1.3
Copper 0.02
Iron 0.03
Nickel 0.001
Other metallic elements
      each 0.05
      total 0.30
Magnesium - Balance -
Zinc 65.4

Some samples of commercially available Magnesium anodes.

 

Table 5.3: Composition of Zinc Anode

Element Percentage (%)
Aluminum 0.005 max
Cadmium 0.003
Iron 0.001
Lead 0.003
Zinc - Balance -

Some samples of Zinc anodes.

 

 

Detailed components of Zinc sacrificial anode.

 

Table 5.4: Composition of Aluminum Anode

Element Percentage (%)
Silicon 0.11
Iron 0.08 max
Zinc 0.45
Mercury 0.045
Copper 0.006
Aluminum - Balance -

Some samples of Aluminum anodes.

 

 

Magnesium and zinc anodes are available in many sizes, weights and shapes from the manufacturers. Packaged anodes (anode and backfill furnished as complete unit) are standards with most suppliers. Different anode compositions are used for soil and sea water.

The potential of aluminum anode is -1.65 V and the rate of consumption is 6.8 lb/amp/year.